Ambrosio serves as an ambassador for the National Multiple Sclerosis Society. Ambrosio was also selected by AskMen.com as Number 2 out of the "Top 99 Most Desirable Women of 2008". In 2012, she came in 6th on the Forbes top-earning models list, estimated to have earned $6.6 million in one year.
Ambrosio has been engaged to businessman Jamie Mazur since 2008. The couple have two children: daughter Anja Louise Ambrosio Mazur (born August 24, 2008) and son Noah Phoenix Ambrosio Mazur (born May 7, 2012), She is the National Ambassador for the National Multiple Sclerosis Society, She is often cited by the popular media as one of the world's sexiest women. As an Angel, she was chosen as one of People magazine's annual "100 Most Beautiful People in the World" in May 2007.
Enrolling in modeling classes is yet another way that prospective models are found. At the age of 12 Alessandra began her modeling profession and by 15 she was modeling for Dilson Stein. Alessandra went on to win Brazils Elite model look which launched her career. This amazing Brazilian beauty is in high demand and has been featured on several international magazine covers. In addition to being a famous model, Alessandria has appeared on a number of television shows and has even come out with her own swimwear line.